煤炭工程 ›› 2014, Vol. 46 ›› Issue (9): 116-119.doi: 10.11799/ce201409038

• 研究探讨 • 上一篇    下一篇

褐煤与液化残渣共热解对煤气组成的影响研究

常松   

  1. 中国矿业大学(北京)
  • 收稿日期:2014-02-25 修回日期:2014-04-11 出版日期:2014-09-10 发布日期:2014-09-10
  • 通讯作者: 常松 E-mail:changsong323@126.com

Study on the Effect on Gas Composition of Co-pyrolysis of Lignite and Liquefaction Residue

  • Received:2014-02-25 Revised:2014-04-11 Online:2014-09-10 Published:2014-09-10

摘要:

摘 要:为了实现煤直接液化残渣的高值化利用,以褐煤及残渣的热解特性差异为基础,进行褐煤与残渣的共热解试验研究,考察了不同的褐煤/残渣配比和不同热解温度对热解煤气组成的影响,并分析了共热解过程对煤气组成的协同作用规律。结果表明:在600℃,褐煤/残渣的配比为9:1;8:2;7:3;6:4;5:5的条件下,褐煤与液化残渣共热解对H2和CO2产出存在负协同作用,对CH4和CO产出存在正协同作用,7:3和6:4的配比对CmHn产出起到正协同作用,其他配比为负协同作用,发生最大协同作用的配料比为7:3~8:2。在配比为7.5:2.5,温度为500℃~800℃条件下,共热解对H2、CO2和CmHn产出存在负协同作用,对CO产出存在正协同作用,500℃~700℃对CH4产出起到正协同作用,750℃~800℃对CH4产出起到负协同作用。发生最大协同作用的温度为550℃~600℃。

关键词: 关键词: 褐煤, 液化残渣, 共热解, 气体组成, 协同作用

Abstract:

Abstract: In order to make a high value use of liquefaction residue , The study on co-pyrolysis of lignite and liquefaction residue was done based on different pyrolysis characteristics of lignite and liquefaction residue, effects of different ratios of lignite and liquefaction residue and different pyrolysis temperatures on the composition of the gas will be studied,and analyzes the laws of synergies on gas composition of the pyrolysis process. The results show that at the temperature of 600℃and the ratios of 9:1; 8:2; 7:3; 6:4; 5:5, the co-pyrolysis of lignite and liquefaction residue has a negative synergy effect on precipitate of H2 and CO2,and has a positive synergy effect on precipitate of CH4 and CO,ratios of 7:3 and 6:4 has a positive synergy effect on precipitate of CmHn, while other ratios are negative synergy effects, the maximum synergy effect comes at the ratio of 7:3~8:2. At the ratio of 7.5:2.5 and the temperature of 500℃~ 800℃ , the co-pyrolysis of lignite and liquefaction residue has a negative synergy effect on precipitate of H2 、CO2 and CmHn,and has a positive synergy effect on precipitate of CO , temperature of 500℃~700℃ has a positive synergy effect on precipitate of CH4, while 750℃~800℃ has a negative synergy effect on precipitate of CH4. the maximum synergy effect comes at the temperature of 550℃~600℃.

Key words: Key words: lignite, liquefaction residue, co-pyrolysis, composition of gas, synergistic effect